ammonolysis|ammonolyses in English

noun

process of replacing water with ammonia (Chemistry)

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1. Ammonolysis of 1.3-dichlorotetramethyldisilazane leads to octamethylcyclotetrasilazane but surprisingly also to hexamethylcyclotrisilazane.

2. The R3Si–NH2 groups resulting from the ammonolysis reaction form silazane units by splitting off ammonia.

3. For the industrial manufacture of perhydropolysilazane n, ammonolysis in a solvent is the standard process.

4. The ammonolysis of 5-O-acetyl-and 5-O-benzoyl-d-glucofuranosiduronic lactones proceeds with simultaneous acyl migration.

5. In the ammonolysis reaction, large quantities of ammonium chloride are produced and must be removed from the reaction mixture.

6. Acetyl and benzoyl derivatives of 1.2-isopropylidene-α- and methyl-α (and β)-d-glucurone, resp., undergo acyl migration under the conditions of lactone ammonolysis.

7. The invention concerns a high-grade long-duration organic fertilizer and a method of manufacturing it by the oxidative ammonolysis of industrial lignin.

8. The normalKirsanov reaction of fluor-substituted anilines yields fluorinated N-phenyl-trichlorophosphineimines, which on ammonolysis give the corresponding bis(phosphoranylidene) ammonium chlorides [RNH−P(NH2)2]2N+Cl−.

9. Using benzyl- and ethyl chloroformates remarkable differences in acylation rates with various glucuronic acid lactones were observed. The carbethoxy-and carbobenzoxy derivatives thus obtained show no tendency to rearrange under ammonolysis conditions.

10. The ratio of formation of both ringsystems is comparable with the ammonolysis of dimethyldichlorosilane and subject to broad fluctuations which are not controllable by specific concentrations of dimethyldichlorosilane or of 1.3-dichlorotetramethyldisilazane or by changing into alkaline milieu.

11. The present invention relates to isononylamines starting from 2-ethylhexanol, to processes for preparing them by dehydration of 2-ethylhexanol to an octene, subsequent hydroformylation to isononanal, optional subsequent hydrogenation to isononanol, subsequent reductive amination or optional ammonolysis to isononylamines, and to their use as corrosion inhibitors, as assistants in rubber formulations, as vulcanization accelerators and also as additives in lubricants to improve the abrasion resistance of mechanical apparatus operated under elevated pressure.